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ByAssociated Press

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Published: 18:59 GMT, 17 October 2016 | Updated: 19:00 GMT, 17 October 2016

BERLIN (AP) — An explosion at a facility belonging to chemical firm BASF in southwestern Germany killed two people and injured at least six others on Monday, authorities said. Another two still were missing hours after the blast.

The explosion occurred in the late morning at a river harbor in Ludwigshafen that is used to unload flammable liquids and liquefied gas.

Plant manager Uwe Liebelt said it was preceded by a fire in a pipeline between the area where the liquids are unloaded and storage tanks. The explosion happened after the company’s fire service arrived at the scene.

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Smoke and fire rise from a facility belonging to chemical firm BASF in Ludwigshafen, southwestern Germany, Monday Oct. 17, 2016. The company said that several people were injured in a late-morning explosion. (Frank Rumpenhorst/dpa via AP)

“How the explosion happened is not clear at the moment,” Liebelt told reporters. He added that it wasn’t yet known what substances were involved and didn’t elaborate on the identities of the victims.

Earlier in the day, the company had reported that one person had died in the explosion.

BASF confirmed on Monday evening that the death toll had risen to two, spokeswoman Silvie-Kristin Wemper said.

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A large column of black smoke rose over the site. Residents in parts of Ludwigshafen, where BASF is based and has a sprawling plant, and Mannheim, on the other side of the Rhine river, were advised to stay indoors and keep their doors and windows closed.

Smoke and fire rise from a facility belonging to chemical firm BASF in Ludwigshafen, southwestern Germany, Monday Oct. 17, 2016. The company said that several people were injured in a late-morning explosion. (Frank Rumpenhorst/dpa via AP)

Dark smoke rises from a facility belonging to chemical firm BASF in Ludwigshafen, southwestern Germany, Monday Oct. 17, 2016. The company said that several people were injured in a late-morning explosion. (Uwe Anspach/dpa via AP)

Dark smoke and fire rises from a facility belonging to chemical firm BASF in Ludwigshafen, southwestern Germany, Monday Oct. 17, 2016. The company said that several people were injured in a late-morning explosion. (Ralf Teutsch/dpa via AP)

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Dark smoke rises from a facility belonging to chemical firm BASF in Ludwigshafen, southwestern Germany, Monday Oct. 17, 2016. The company said that several people were injured in a late-morning explosion. (Michael Deines/dpa via AP)

Dark smoke rises from a facility belonging to chemical firm BASF in Ludwigshafen, southwestern Germany, Monday Oct. 17, 2016. The company said that several people were injured in a late-morning explosion. (Uwe Anspach/dpa via AP)

FILE – The Feb. 18, 2016 file picture shows parts of BASF chemical plant at Ludwigshafen, Germany. Chemical company BASF says several people have been injured in an explosion at a facility in southwestern Germany. Company spokeswoman Ursula von Stetten said the explosion occurred late Monday morning Oct. 17, 2016 at a river harbor in Ludwigshafen, where BASF is based, that is used to unload flammable liquids and liquid gas. ( Uwe Anspach/dpa via AP,file)

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